cyclization reactions造句
例句與造句
- Short Synthesis of Skeletally and Stereochemically Diverse Small Molecules by Coupling Petasis Condensation Reactions to Cyclization Reactions
- The conditions under which these cyclization reactions occur follow Baldwin's rules for ring closure.
- Squalene, through a cyclization reaction with 2, 3-oxidosqualene 6 as an intermediate forms cycloartenol.
- The racemic synthesis involves addition / cyclization reaction of 2-amino-1-phenylethanol with cyanogen bromide.
- Many radiomimetic compounds are enediynes, which undergo the Bergman cyclization reaction to produce the para-benzyne diradical.
- It's difficult to find cyclization reactions in a sentence. 用cyclization reactions造句挺難的
- His group has also reported on the use of metal-hydride bonds as radical initiators of cyclization reactions.
- The silicon-directed Nazarov cyclization reaction was subsequently employed in the synthesis of the natural product Silphinene, shown below.
- An example of the latter case is shown below for the torquoselective Nazarov cyclization reaction of a chiral allenyl vinyl ketone.
- Finally, an unusual ER catalyzed cyclization reaction, purported to go through a substitution like mechanism, forms the cyclopropane ring.
- When the dipole and dipolarophile are part of the same molecule, an intramolecular cyclization reaction can lead to a polycyclic product of considerable complexity.
- Geranyl pyrophosphate can also undergo two sequential cyclization reactions to form bicyclic monoterpenes, such as pinene which is the primary constituent of pine resin.
- "' Delta-cadinene synthase "', a sesquiterpene cyclase, is an enzyme expressed in plants that catalyzes a cyclization reaction in terpenoid biosynthesis.
- The catalytic mechanism uses coupled aspartate and histidine residues to initiate the cyclization reaction by protonating at C3 and deprotonating at C29, proceeding through a discrete series of carbocation intermediates.
- The second cyclization reaction yields a mixture of diastereomers with the general structure depicted above, the predominant ones being ( 2R, 3R ) and ( 2S, 3S ).
- The course of the templated cyclization depends on the presence of metal ion, which is provide directional influence, therefore acting as a'template'for the cyclization reaction.
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